Two new luminescent Cd(II)-based coordination polymers by regulating the asymmetrical tetracarboxylate and auxiliary ligands displaying high sensitivity for Fe3+ and CrO42-

Two new coordination polymers (CPs), namely [Cd-2(L)(2,2'-bipy)] (1) and [Cd-2(L)(H2O)(4)] (2) (H4L = [1,1'-biphenyl]-2,3,3',5'-tetracarboxylic acid and 2,2'- bipy = 2,2'-bipyridine), have been successfully synthesized under solvothermal conditions. 1 exhibits a 2D layer that was further extended into a 3D supramolecular framework through the packing interaction. 2 has a 3D 3,3,4-c network with a point symbol of (6(2).8(2))(6(3))(2). The sensing results illustrated that both of them could be prospective candidates for developing luminescent sensors for the probing of Fe3+ and CrO42-. The probe effects remained highly selective to the Fe3+ and CrO42- ions even if there are other interfering ions. The limits of detection (LODs) for Fe3+/CrO42- were calculated to be ca. 2.47 x 10(-8) M-1/1.12 x 10(-8) M-1 and 1.35 x 10(-9) M-1/2.23 x 10(-8) M-1 for 1 and 2, respectively. The fluorescence resonance energy transfer process may be the major pathway behind the quenching mechanism for Fe3+ and CrO42- ions. The recycling operation indicated that compounds 1 and 2 are promising reusable probes for their effective capability of detecting Fe3+ and CrO42- ions.

Automated summary

Two new coordination polymers (CPs), 1 and 2, have been successfully synthesized, showing promising capabilities in detecting Fe3+ and CrO42- ions with high selectivity and reusability. The sensing results indicate that both CPs could be prospective candidates for developing luminescent sensors.