期刊
FLUID PHASE EQUILIBRIA
卷 448, 期 -, 页码 99-104出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.fluid.2017.05.008
关键词
Deep eutectic solvents; Thermodynamics; Phase transfer; Extraction
Deep eutectic solvents (DESs) have been used for the purification of oils and the extraction of active ingredients from natural products but little is known about the mechanism of the extraction process. In this study a variety of molecular solutes are dissolved in alkanes and the thermodynamics of transfer into six DESs have been quantified. It is shown that the transfer of most solutes into the DES is endothermic and driven by entropy. The largest partition coefficients were demonstrated by the liquids with the lowest surface tensions and this is thought to arise because the enthalpy of hole formation controls the rate of solute transfer. Accordingly, it was shown that the size of the solute has an effect on the partition coefficient with smaller solutes partitioning preferably into the DES. As expected, solutes capable of strongly hydrogen bonding partitioned much better into the DES as the enthalpy of transfer was negative. (C) 2017 Elsevier B.V. All rights reserved.
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