Nickel complexes based on BIAN ligands: transformation and catalysis on ethylene polymerization

Treatment of bis(arylimino)acenaphthene ((Ar)BIAN) with Ni(COD)(2) in toluene afforded (dmp)BIANNi(COD) (2a, dmp = 2,6-Me2C6H3) and (dipp)BIANNi(COD) (2b, dipp = 2,6-(PrC6H3)-Pr-i), respectively, in moderate yields. Complexes 2a and 2b can be oxidized by a small amount of oxygen at low temperature leading to oxygen-bridged dinuclear Ni(ii) complexes ((dmp)BIANNi)(2)(mu-O)(2) (4a) and ((dipp)BIANNi)(2)(mu-O)(2) (4b), respectively, as a purple powder. The reaction of (Ar)BIAN with 0.5 equiv of Ni(COD)(2) or Ni(Ph3P)(4) gave bisligated complexes ((dmp)BIAN)(2)Ni (3a) and ((dipp)BIAN)(2)Ni (3b), which can be considered as Ni(0) complexes supported by two neutral BIAN ligands. Oxidation of the bisligated nickel complexes 3a and 3b with [Cp2Fe][B(C6F5)(4)] afforded cationic Ni(i) complexes [((dmp)BIAN)(2)Ni][B(C6F5)(4)] (5a) and [((dipp)BIAN)(2)Ni][B(C6F5)(4)] (5b), respectively, in which the Ni(i) centre is chelated by two neutral Ar-BIAN ligands. These complexes were characterized by NMR and IR spectroscopy and DFT calculation, and the molecular structures of 3b, 4b, and 5b were well established by X-ray diffraction analysis. These complexes were evaluated as catalysts for ethylene polymerization in which 2b showed high activity in the presence of AlMe3. C-13 NMR analysis of polymers showed that the 2b/AlMe3 catalytic system gave less-branched polymers when compared to that obtained with (dipp)BIANNiBr(2) under the same conditions.

Automated summary

In this study, two new oxygen-bridged dinuclear Ni(ii) complexes were successfully synthesized by reaction with oxygen in solvent, along with Ni(0) and Ni(i) complexes supported by two neutral ligands. These complexes showed promising catalytic performance at low temperatures.