4.6 Article

From photosensitizers to light harvesters adapting the molecular structure in all-BODIPY assemblies

期刊

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 23, 期 19, 页码 11191-11195

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cp00991e

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资金

  1. Ministerio de Ciencia e Innovacion of Spain [MAT2017-83856-C3, PID2020-114755GB-C3]
  2. Gobierno Vasco [IT912-16]
  3. Ministerio de Ciencia e Innovacion

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This paper presents a protocol for designing dyads and triads based on BODIPY dyes as singlet oxygen photosensitizers or energy transfer molecular cassettes without halogens. Photonic characterization shows the crucial role of the BODIPY-BODIPY linkage in finely modulating the balance between the triplet state population and fluorescence decay.
Herein we detail a protocol to design dyads and triads based solely on BODIPY dyes as halogen-free singlet oxygen photosensitizers or energy transfer molecular cassettes. The conducted photonic characterization reveals the key role of the BODIPY-BODIPY linkage to finely modulate the balance between the triplet state population and fluorescence decay.

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