期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 45, 页码 5582-5585出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01806j
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A metal-free, three-component trifluoromethylative alkenylation reaction using beta-nitrostyrenes with unactivated alkenes has been developed under visible light, providing a series of trifluoromethylated aromatic alkenes in good to excellent yields.
A three-component and redox-neutral trifluoromethylative alkenylation of unactivated alkenes with beta-nitrostyrenes has been developed under visible-light. This metal-free protocol utilizes the easy to handle Langlois reagent (CF3SO2Na) as the CF3 source and is suitable for various unactivated alkenes and beta-nitrostyrenes, affording a series of trifluoromethylated aromatic alkenes under mild conditions in good to excellent yields.
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