期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 30, 页码 3712-3715出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc07862j
关键词
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A new 3D noncentrosymmetric mixed-metal sulfate iodate, AgBi(SO4)(IO3)(2), has been designed by aliovalent substitution based on a 2D iodate of AgBi(IO3)(4). The enhancement of second harmonic generation response and the retention of a favorable NLO framework demonstrate a novel strategy for upgrading structural dimensions.
A new 3D noncentrosymmetric mixed-metal sulfate iodate, AgBi(SO4)(IO3)(2), has been designed based on a 2D iodate of AgBi(IO3)(4)via the aliovalent substitution of [IO3](-) groups by [SO4](2-) groups. Enhancement of the second harmonic generation response (3.0 x KDP to 3.9 x KDP) has been achieved while retaining a favorable NLO framework. This is a novel strategy to upgrade structural dimensions.
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