Covalent triazine frameworks constructed via benzyl halide monomers showing high photocatalytic activity in biomass reforming

Here we report the synthesis of covalent triazine frameworks (CTFs) using benzyl halide monomers which are more cost-effective and with higher availability than previous ones. The resulting CTFs were successfully applied for efficient photocatalytic reforming of glucose for the first time, with a high hydrogen evolution rate up to 330 mu mol g(-1) h(-1) under pH = 12. This work presented a new way to synthesize CTFs and further exhibited their potential applications in photocatalytic biomass reforming.

Automated summary

This study reported the synthesis of covalent triazine frameworks (CTFs) using benzyl halide monomers, which are more cost-effective and readily available than previous ones, for efficient photocatalytic reforming of glucose. The resulting CTFs demonstrated a high hydrogen evolution rate up to 330 mu mol g(-1) h(-1) under pH = 12, showcasing potential applications in photocatalytic biomass reforming.