Realizing 6.7 wt% reversible storage of hydrogen at ambient temperature with non-confined ultrafine magnesium hydrides

Using light metal hydrides as hydrogen carriers is of particular interest for safe and compact storage of hydrogen. Magnesium hydride (MgH2) has attracted significant attention due to its 7.6 wt% hydrogen content and the natural abundance of Mg. However, bulk MgH2 is stable (Delta H-f similar to 76 kJ mol(-1)) and releases hydrogen only at impractically high temperatures (>300 degrees C). Herein, we demonstrate a first attempt to achieve ambient-temperature reversibility of hydrogen storage for MgH2 by fabricating non-confined ultrafine nanoparticles. Taking advantage of the big discrepancies in the solubility of metal hydrides and chlorides in THF, a novel metathesis process of liquid-solid phase driven by ultrasound was proposed. Ultrafine MgH2 nanoparticles predominantly of around 4-5 nm in size were successfully obtained without scaffolds or supports. A reversible hydrogen storage capacity of 6.7 wt% at 30 degrees C was measured, which has never been achieved before, thanks to thermodynamic destabilization and decreased kinetic barriers. The bare nanoparticles exhibited a stable and rapid hydrogen cycling behaviour in 50 cycles at 150 degrees C, a remarkable improvement compared with bulk MgH2. Our finding brings MgH2 a step closer to practical applications and the methodology presented here opens new pathways for fabricating sensitive nanoparticles.

Automated summary

Using ultrafine magnesium hydride nanoparticles without scaffolds or supports, reversible hydrogen storage at ambient temperature with a capacity of 6.7 wt% was achieved, thanks to thermodynamic destabilization and decreased kinetic barriers. The nanoparticles exhibited stable and rapid hydrogen cycling behavior at 150 degrees C, showing a significant improvement compared to bulk MgH2. This study brings magnesium hydride closer to practical applications and introduces new pathways for fabricating sensitive nanoparticles.