期刊
ORGANIC CHEMISTRY FRONTIERS
卷 8, 期 13, 页码 3469-3474出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00394a
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资金
- Special Funds of the Taishan Scholar Program of Shandong Province [tsqn201812047]
- Guangdong Provincial Key Laboratory of Catalysis [2020B121201002]
A chiral phosphoric acid-catalyzed enantioselective 1,6-conjugate addition of thiolacetic acid to alkynyl indole imine methide in situ formed from alpha-(3-indolyl) propargylic alcohol has been developed, enabling the formation of axially chiral sulfur-containing tetrasubstituted allenes in generally high efficiency with stereoselectivity.
A chiral phosphoric acid-catalyzed enantioselective 1,6-conjugate addition of thiolacetic acid to alkynyl indole imine methide in situ formed from alpha-(3-indolyl) propargylic alcohol has been established, which enables the formation of axially chiral sulfur-containing tetrasubstituted allenes in generally high efficiency with stereoselectivity.
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