Slow pyrolysis of an LDPE/PP mixture: Kinetics and process performance

High- and low-density polyethylene (HDPE and LDPE) and polypropylene (PP) are the most common polymers among plastic waste as they have multiple commercial applications. This study focused on thermal degradation characteristics and kinetic of a plastic mixture with a composition of 92.5 wt% LDPE and 7.5% PP. Thermal decomposition characteristics of the plastic mixture was analysed through thermogravimetric analysis (TGA). The overall kinetic of the process was studied using the modified Coats-Redfern method and the Ozawa-Flynn-Wall (OFW) method. The apparent activation energy (E) and pre-exponential factor (A) obtained were 316.0 kJ/mol; 8.09+21 min(-1) and 311.5 kJ/mol; 4.35+21 min(-1), respectively. Slow pyrolysis of the analysed mixture was carried out in a semi-batch reactor under atmospheric pressure and nitrogen atmosphere and three different pyrolysis temperatures were investigated: 420 degrees C, 450 degrees C and 500 degrees C. H-2, CH4, C2H4, C2H6 and C3H8 were the main components of the gas phase. Liquid (oil/wax phase) yields increased with increasing operative temperature from 42% at 420 degrees C to 62% at 500 degrees C. On the other hand, solid phase showed a specular behaviour compared to the oil/wax phase, decreasing from 21% to 5% in the considered temperature range. On the contrary, gas phase did not change much with pyrolysis temperature, with a decrease from 37% at 420 degrees C to 34% at 500 degrees C. Products' energy yields were also estimated at 420 degrees C. They ranged from 7.4% to 37.8% and 43.0% for solid, gas and oil fraction, respectively. Oil fraction collected from pyrolysis at 420 degrees C was also characterized. (c) 2021 Energy Institute. Published by Elsevier Ltd. All rights reserved.

Automated summary

This study focused on the thermal degradation characteristics and kinetic of a plastic mixture primarily composed of LDPE and PP, finding that liquid yield increased with temperature while solid and gas phase yields decreased accordingly.