4.7 Article

Ni-Catalyzed asymmetric hetero-Diels-Alder reactions of conjugated vinyl azides: synthesis of chiral azido polycycles

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ORGANIC CHEMISTRY FRONTIERS
卷 8, 期 8, 页码 1770-1774

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo01597k

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资金

  1. Natural Science Foundation of China
  2. Shandong province [21971149, ZR2018MB010, ZR2019ZD45, ZR2019BB060]
  3. Tang scholar award
  4. Fundamental Research Funds of Shandong University

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The efficient Ni(ii)/Feng ligand-catalyzed asymmetric hetero-Diels-Alder reaction between conjugated vinyl azides and carbonyl groups reported in this study provides a platform for the synthesis of complicated chiral azido polycycles in high yields and excellent enantioselectivities.
We report herein an efficient Ni(ii)/Feng ligand-catalyzed asymmetric hetero-Diels-Alder reaction between conjugated vinyl azides and carbonyl groups. This method provides a platform for the synthesis of complicated chiral azido polycycles in high yields and excellent enantioselectivities.

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