Tuning the intermediate reaction barriers by a CuPd catalyst to improve the selectivity of CO2 electroreduction to C2 products

Electrochemical CO2 reduction is a promising strategy for the utilization of CO2 and intermittent excess electricity. Cu is the only single metal catalyst that can electrochemically convert CO2 into multicarbon products. However, Cu exhibits an unfavorable activity and selectivity for the generation of C-2 products because of the insufficient amount of CO* provided for the C-C coupling. Based on the strong CO2 adsorption and ultrafast reaction kinetics of CO* formation on Pd, an intimate CuPd(100) interface was designed to lower the intermediate reaction barriers and improve the efficiency of C-2 product formation. Density functional theory (DFT) calculations showed that the CuPd(100) interface enhanced the CO2 adsorption and decreased the CO2* hydrogenation energy barrier, which was beneficial for the C-C coupling. The potential-determining step (PDS) barrier of CO2 to C-2 products on the CuPd(100) interface was 0.61 eV, which was lower than that on Cu(100) (0.72 eV). Encouraged by the DFT calculation results, the CuPd(100) interface catalyst was prepared by a facile chemical solution method and characterized by transmission electron microscopy. CO2 temperature-programmed desorption and gas sensor experiments further confirmed the enhancement of the CO2 adsorption and CO2* hydrogenation ability of the CuPd(100) interface catalyst. Specifically, the obtained CuPd(100) interface catalyst exhibited a C-2 Faradaic efficiency of 50.3% +/- 1.2% at.1.4 V-RHE in 0.1 M KHCO3, which was 2.1 times higher than that of the Cu catalyst (23.6% +/- 1.5%). This study provides the basis for the rational design of Cu-based electrocatalysts for the generation of multicarbon products by fine-tuning the intermediate reaction barriers. (C) 2021, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

Automated summary

This study successfully improved the efficiency and Faradaic efficiency of C-2 products by designing a CuPd(100) interface catalyst, laying the foundation for the rational design of Cu-based electrocatalysts for the generation of multicarbon products.