Controlling the degree of rotational directionality in laser-induced molecular dynamics

We demonstrate experimentally a method of varying the degree of directionality in laser-induced molecular rotation. To control the ratio between the number of clockwise and counterclockwise rotating molecules (with respect to a fixed laboratory axis), we change the polarization ellipticity of the laser field of an optical centrifuge. The experimental data, supported by numerical simulations, show that the degree of rotational directionality can be varied in a continuous fashion between unidirectional and bidirectional rotation. The control can be executed with no significant loss in the total number of rotating molecules. The technique could be used for studying the effects of orientation of the molecular angular momentum on molecular collisions and chemical reactions. It could also be utilized for controlling magnetic and optical properties of gases, as well as for the enantioselective detection of chiral molecules.

Automated summary

This study demonstrates a method for varying the directionality of laser-induced molecular rotation by changing the polarization ellipticity of the laser field in an optical centrifuge. The results show that the degree of rotational directionality can be continuously adjusted between unidirectional and bidirectional rotation without significant loss in the total number of rotating molecules. This technique could be applied to study the effects of molecular angular momentum orientation on collisions and reactions, as well as for controlling magnetic and optical properties of gases and enantioselective detection of chiral molecules.