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Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage
William Cullen et al.
NATURE CHEMISTRY (2016)
A Fluorescent and Switchable Rotaxane Dual Organocatalyst
Chak-Shing Kwan et al.
ORGANIC LETTERS (2016)
A concerted two-prong approach to the in situ allosteric regulation of bifunctional catalysis
C. Michael McGuirk et al.
CHEMICAL SCIENCE (2016)
A Self-Assembled Molecular Cage for Substrate-Selective Epoxidation Reactions in Aqueous Media
Petrus F. Kuijpers et al.
ACS CATALYSIS (2016)
Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities
John F. Hartwig et al.
ACS CENTRAL SCIENCE (2016)
Cation-Triggered Switchable Asymmetric Catalysis with Chiral Aza-CrownPhos
Guang-Hui Ouyang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)
A Stimuli-Responsive Rotaxane-Gold Catalyst: Regulation of Activity and Diastereoselectivity
Marzia Galli et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)
Substrate selective amide coupling driven by encapsulation of a coupling agent within a self-assembled hexameric capsule
Sonia Giust et al.
CHEMICAL COMMUNICATIONS (2015)
Supramolecular Catalysis in Metal-Ligand Cluster Hosts
Casey J. Brown et al.
CHEMICAL REVIEWS (2015)
Artificial Molecular Machines
Sundus Erbas-Cakmak et al.
CHEMICAL REVIEWS (2015)
Artificial switchable catalysts
Victor Blanco et al.
CHEMICAL SOCIETY REVIEWS (2015)
Supramolecular Ga4L612- Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer
Derek M. Dalton et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
A Deep Cavitand Templates Lactam Formation in Water
Simone Mosca et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage
Cristina Garcia-Simon et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)
Terpene cyclization catalysed inside a self-assembled cavity
Q. Zhang et al.
NATURE CHEMISTRY (2015)
A meta-selective C-H borylation directed by a secondary interaction between ligand and substrate
Yoichiro Kuninobu et al.
NATURE CHEMISTRY (2015)
A supramolecular microenvironment strategy for transition metal catalysis
David M. Kaphan et al.
SCIENCE (2015)
Selecting reactions and reactants using a switchable rotaxane organocatalyst with two different active sites
Jack Beswick et al.
CHEMICAL SCIENCE (2015)
Molecular computing: paths to chemical Turing machines
Shaji Varghese et al.
CHEMICAL SCIENCE (2015)
An allosteric photoredox catalyst inspired by photosynthetic machinery
Alejo M. Lifschitz et al.
NATURE COMMUNICATIONS (2015)
Dynamic control of chirality in phosphine ligands for enantioselective catalysis
Depeng Zhao et al.
NATURE COMMUNICATIONS (2015)
Processive Catalysis
Stijn F. M. van Dongen et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
A Toggle Nanoswitch Alternately Controlling Two Catalytic Reactions
Soumen De et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)
Chemical consequences of mechanical bonding in catenanes and rotaxanes: isomerism, modification, catalysis and molecular machines for synthesis
Edward A. Neal et al.
CHEMICAL COMMUNICATIONS (2014)
Dual stereocontrol over the Henry reaction using a light- and heat-triggered organocatalyst
Matea Vlatkovic et al.
CHEMICAL COMMUNICATIONS (2014)
Review: A History of Cyclodextrins
Gregorio Crini
CHEMICAL REVIEWS (2014)
Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts
Matthieu Raynal et al.
CHEMICAL SOCIETY REVIEWS (2014)
Supramolecular catalysis. Part 2: artificial enzyme mimics
Matthieu Raynal et al.
CHEMICAL SOCIETY REVIEWS (2014)
Origins of Large Rate Enhancements in the Nazarov Cyclization Catalyzed by Supramolecular Encapsulation
Courtney J. Hastings et al.
CHEMISTRY-A EUROPEAN JOURNAL (2014)
Substrate-Selective Catalysis
Emil Lindback et al.
CHEMISTRY-A EUROPEAN JOURNAL (2014)
Encapsulated Cobalt-Porphyrin as a Catalyst for Size-Selective Radical-type Cyclopropanation Reactions
Matthias Otte et al.
CHEMISTRY-A EUROPEAN JOURNAL (2014)
A monomer-dimer nanoswitch that mimics the working principle of the SARS-CoV 3CLpro enzyme controls copper-catalysed cyclopropanation
Soumen De et al.
DALTON TRANSACTIONS (2014)
Supramolecular Control of Reactivity and Catalysis - Effective Molarities of Recognition-Mediated Bimolecular Reactions
Stefano Di Stefano et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2014)
Efficient Assembly of Threaded Molecular Machines for Sequence-Specific Synthesis
Guillaume De Bo et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Nucleophilic Substitution Catalyzed by a Supramolecular Cavity Proceeds with Retention of Absolute Stereochemistry
Chen Zhao et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
A Switchable [2]Rotaxane Asymmetric Organocatalyst That Utilizes an Acyclic Chiral Secondary Amine
Victor Blanco et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Allosteric Regulation of Supramolecular Oligomerization and Catalytic Activity via Coordination-Based Control of Competitive Hydrogen-Bonding Events
C. Michael McGuirk et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Small Molecule Regulation of Self-Association and Catalytic Activity in a Supramolecular Coordination Complex
C. Michael McGuirk et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)
Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of contiguous all-carbon quaternary stereocentres
Kohsuke Ohmatsu et al.
NATURE CHEMISTRY (2014)
Organometallics Roundtable 2013-2014
John A. Gladysz et al.
ORGANOMETALLICS (2014)
Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization
Pawel Dydio et al.
CHEMICAL SCIENCE (2014)
Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of 5-Vinyloxazolidinones with Imines Using Chiral Ammonium-Phosphine Hybrid Ligand
Kohsuke Ohmatsu et al.
ACS CATALYSIS (2014)
Rotaxane Catalysts
David A. Leigh et al.
ACS CATALYSIS (2014)
NHC-Capped Cyclodextrins (ICyDs): Insulated Metal Complexes, Commutable Multicoordination Sphere, and Cavity-Dependent Catalysis
Maxime Guitet et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Enantiopure Water-Soluble [Fe4L6] Cages: Host-Guest Chemistry and Catalytic Activity
Jeanne L. Bolliger et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Comparison of laboratory delignification methods, their selectivity, and impacts on physiochemical characteristics of cellulosic biomass
Rajeev Kumar et al.
BIORESOURCE TECHNOLOGY (2013)
Oxidation of cycloalkanes by H2O2 using a copper-hemicryptophane complex as a catalyst
Olivier Perraud et al.
CHEMICAL COMMUNICATIONS (2013)
Hydrogen-bond mediated regio- and enantioselectivity in a C-H amination reaction catalysed by a supramolecular Rh(II) complex
Thorsten Hoeke et al.
CHEMICAL COMMUNICATIONS (2013)
Hexameric Resorcinarene Capsule is a Bronsted Acid: Investigation and Application to Synthesis and Catalysis
Qi Zhang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
Precise Supramolecular Control of Selectivity in the Rh-Catalyzed Hydroformylation of Terminal and Internal Alkenes
Pawel Dydio et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
A Self-Organizing Chemical Assembly Line
Airton G. Salles et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)
A supramolecular approach to combining enzymatic and transition metal catalysis
Z. Jane Wang et al.
NATURE CHEMISTRY (2013)
Sequence-Specific Peptide Synthesis by an Artificial Small-Molecule Machine
Bartosz Lewandowski et al.
SCIENCE (2013)
Capsule-controlled selectivity of a rhodium hydroformylation catalyst
Vladica Bocokic et al.
NATURE COMMUNICATIONS (2013)
Substrate selectivity in the alkyne hydration mediated by NHC-Au(I) controlled by encapsulation of the catalyst within a hydrogen bonded hexameric host
Alessandra Cavarzan et al.
CATALYSIS SCIENCE & TECHNOLOGY (2013)
Innate and Guided C-H Functionalization Logic
Tobias Brueckl et al.
ACCOUNTS OF CHEMICAL RESEARCH (2012)
Controlling Site Selectivity in Palladium-Catalyzed C-H Bond Functionalization
Sharon R. Neufeldt et al.
ACCOUNTS OF CHEMICAL RESEARCH (2012)
A Rotaxane-Based Switchable Organocatalyst
Victor Blanco et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)
Production of 1,5-pentanediol from biomass via furfural and tetrahydrofurfuryl alcohol
Yoshinao Nakagawa et al.
CATALYSIS TODAY (2012)
A reversible nanoswitch as an ON-OFF photocatalyst
Michael Schmittel et al.
CHEMICAL COMMUNICATIONS (2012)
Applied Hydroformylation
Robert Franke et al.
CHEMICAL REVIEWS (2012)
Self-Assembled Pd6 Open Cage with Triimidazole Walls and the Use of Its Confined Nanospace for Catalytic Knoevenagel- and Diels-Alder Reactions in Aqueous Medium
Dipak Samanta et al.
CHEMISTRY-A EUROPEAN JOURNAL (2012)
Cage-Catalyzed Knoevenagel Condensation under Neutral Conditions in Water
Takashi Murase et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Selective Monoterpene-like Cyclization Reactions Achieved by Water Exclusion from Reactive Intermediates in a Supramolecular Catalyst
William M. Hart-Cooper et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)
Engineering the third wave of biocatalysis
U. T. Bornscheuer et al.
NATURE (2012)
Combinatorial evolution of site- and enantioselective catalysts for polyene epoxidation
Phillip A. Lichtor et al.
NATURE CHEMISTRY (2012)
Adding Aliphatic C-H Bond Oxidations to Synthesis
M. Christina White
SCIENCE (2012)
Catalytic materials that improve selectivity of biomass conversions
Saikat Dutta
RSC ADVANCES (2012)
Laboratory Evolution of Stereoselective Enzymes: A Prolific Source of Catalysts for Asymmetric Reactions
Manfred T. Reetz
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
Switchable Catalysis with a Light-Responsive Cavitand
Orion B. Berryman et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
If C-H Bonds Could Talk: Selective C-H Bond Oxidation
Timothy Newhouse et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes
Pawel Dydio et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)
Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles
Rajesh Chakrabarty et al.
CHEMICAL REVIEWS (2011)
C-H functionalization logic in total synthesis
Will R. Gutekunst et al.
CHEMICAL SOCIETY REVIEWS (2011)
Regioselectivity of the borylation of alkanes and arenes
John F. Hartwig
CHEMICAL SOCIETY REVIEWS (2011)
Predictable Stereoselective and Chemoselective Hydroxylations and Epoxidations with P450 3A4
Aaron T. Larsen et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Cofactor-Controlled Enantioselective Catalysis
Pawel Dydio et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Supramolecular Control on Chemo- and Regioselectivity via Encapsulation of (NHC)-Au Catalyst within a Hexameric Self-Assembled Host
Alessandra Cavarzan et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)
Dynamic Control of Chiral Space in a Catalytic Asymmetric Reaction Using a Molecular Motor
Jiaobing Wang et al.
SCIENCE (2011)
One-Bead-One-Catalyst Approach to Aspartic Acid-Based Oxidation Catalyst Discovery
Phillip A. Lichtor et al.
ACS COMBINATORIAL SCIENCE (2011)
Both [2+2] and [2+4] additions of inert aromatics via identical ternary host-guest complexes
Shinnosuke Horiuchi et al.
CHEMICAL COMMUNICATIONS (2010)
Transition-State Stabilization by a Secondary Substrate-Ligand Interaction: A New Design Principle for Highly Efficient Transition-Metal Catalysis
Tomas Smejkal et al.
CHEMISTRY-A EUROPEAN JOURNAL (2010)
Cyclodextrins as Supramolecular Organo-Catalysts
L. Marinescu et al.
CURRENT ORGANIC CHEMISTRY (2010)
Naphthalene Diels-Alder in a Self-Assembled Molecular Flask
Takashi Murase et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Porphyrin Macrocyclic Catalysts for the Processive Oxidation of Polymer Substrates
Cyrille Monnereau et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Enzymelike Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation
Courtney J. Hastings et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)
Template synthesis of precisely monodisperse silica nanoparticles within self-assembled organometallic spheres
Kosuke Suzuki et al.
NATURE CHEMISTRY (2010)
Supramolecular catalysis beyond enzyme mimics
Jurjen Meeuwissen et al.
NATURE CHEMISTRY (2010)
Allosteric Supramolecular Triple-Layer Catalysts
Hyo Jae Yoon et al.
SCIENCE (2010)
Light-Driven Enantioselective Organocatalysis
Christiane Mueller et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)
Analysis of Transient and Catalytic Desosamine-binding Pockets in Cytochrome P-450 PikC from Streptomyces venezuelae
Shengying Li et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2009)
Recognition and Organocatalysis with a Synthetic Cavitand Receptor
Fernando R. Pinacho Crisostomo et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)
Enantioselective Catalysis of the Aza-Cope Rearrangement by a Chiral Supramolecular Assembly
Casey J. Brown et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)
White Phosphorus Is Air-Stable Within a Self-Assembled Tetrahedral Capsule
Prasenjit Mal et al.
SCIENCE (2009)
Highly selective photomediated 1,4-radical addition to o-quinones controlled by a self-assembled cage
Takumi Yamaguchi et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
A supramolecular catalyst for regioselective hydroformylation of unsaturated carboxylic acids
Tomas Smejkal et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)
The rate-determining step in the rhodium-xantphos-catalysed hydroformylation of 1-octene
Erik Zuidema et al.
CHEMISTRY-A EUROPEAN JOURNAL (2008)
Supramolecular catalysis of orthoformate hydrolysis in basic solution: An enzyme-like mechanism
Michael D. Pluth et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
PCR-like cascade reactions in the context of an allosteric enzyme mimic
Hyo Jae Yoon et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
Aza cope rearrangement of propargyl enammonium cations catalyzed by a self-assembled nanozyme
Courtney J. Hastings et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
Asymmetric [2+2] olefin cross photoaddition in a self-assembled host with remote chiral auxiliaries
Yuki Nishioka et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
Organocatalysis in a synthetic receptor with an inwardly directed carboxylic acid
Siddhartha R. Shenoy et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
Reaction of isonitriles with carboxylic acids in a cavitand: Observation of elusive isoimide intermediates
Per Restorp et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)
Mechanism of Threading a Polymer Through a Macrocyclic Ring
Alexander B. C. Deutman et al.
SCIENCE (2008)
Stabilization of labile carbonyl addition intermediates by a synthetic receptor
Tetsuo Iwasawa et al.
SCIENCE (2007)
Unusual [2+4] and [2+2] cycloadditions of arenes in the confined cavity of self-assembled cages
Yuki Nishioka et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)
Acid catalysis in basic solution: A supramolecular host promotes orthoformate hydrolysis
Michael D. Pluth et al.
SCIENCE (2007)
The confined cavity of a coordination cage suppresses the photocleavage of alpha-diketones to give cyclization products through kinetically unfavorable pathways
Takahito Furusawa et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)
The structural basis for substrate anchoring, active site selectivity, and product formation by P450 PikC from Streptomyces venezuelae
David H. Sherman et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2006)
High-precision catalysts: Regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes
Mark Kuil et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)
Photochemistry of 4-(2′-aminoethyl)quinolones:: Enantioselective synthesis of tetracyclic tetrahydro-1aH-pyrido[4′,3′:2,3]-cyclobuta[1,2-c] quinoline-2,11(3H,8H)-diones by Intra- and Intermolecular [2+2]-photocycloaddition reactions in solution
Philipp Selig et al.
JOURNAL OF ORGANIC CHEMISTRY (2006)
Molecular recognition in the selective oxygenation of saturated C-H bonds by a dimanganese catalyst
Siddhartha Das et al.
SCIENCE (2006)
Diels-alder in aqueous molecular hosts: Unusual regioselectivity and efficient catalysis
M Yoshizawa et al.
SCIENCE (2006)
C-H bond functionalization in complex organic synthesis
K Godula et al.
SCIENCE (2006)
Organocatalytic enantioselective photoreactions
P Wessig
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)
Catalytic enantioselective reactions driven by photoinduced electron transfer
A Bauer et al.
NATURE (2005)
Concurrent tandem catalysis
JC Wasilke et al.
CHEMICAL REVIEWS (2005)
Signal amplification and detection via a supramolecular allosteric catalyst
NC Gianneschi et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Effective molarities in supramolecular catalysis of two-substrate reactions
R Cacciapaglia et al.
ACCOUNTS OF CHEMICAL RESEARCH (2004)
Alkane oxidation via photochemical excitation of a self-assembled molecular cage
M Yoshizawa et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
Supramolecular catalysis of a unimolecular transformation: Aza-cope rearrangement within a self-assembled host
D Fiedler et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)
Epoxidation of polybutadiene by a topologically linked catalyst
P Thordarson et al.
NATURE (2003)
Cavity-directed synthesis within a self-assembled coordination cage: Highly selective [2+2] cross-photodimerization of olefins
M Yoshizawa et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
The bis-barium complex of a butterfly crown ether as a phototunable supramolecular catalyst
R Cacciapaglia et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Supramolecular catalysis of the enantiodifferentiating [4+4] photocyclodimerization of 2-anthracenecarboxylate by γ-cyclodextrin
A Nakamura et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
On inventing reactions for atom economy
BM Trost
ACCOUNTS OF CHEMICAL RESEARCH (2002)
Catalytic oxidations of steroid substrates by artificial cytochrome P-450 enzymes
J Yang et al.
JOURNAL OF ORGANIC CHEMISTRY (2002)
Understanding and exploiting C-H bond activation
JA Labinger et al.
NATURE (2002)
A view at the millennium: The efficiency of enzymatic catalysis
TC Bruice
ACCOUNTS OF CHEMICAL RESEARCH (2002)
Hybrid QM/MM study of propene insertion into the Rh-H bond of HRh(PPh3)2(CO)(η2-CH2=CHCH3):: the role of the olefin adduct in determining product selectivity
SA Decker et al.
JOURNAL OF ORGANOMETALLIC CHEMISTRY (2001)
Unraveling the origin of regioselectivity in rhodium diphosphine catalyzed hydroformylation.: A DFT QM/MM study
JJ Carbó et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Enantioselective photochemical reactions of 2-pyridones in solution
T Bach et al.
ORGANIC LETTERS (2001)
Industrial biocatalysis today and tomorrow
A Schmid et al.
NATURE (2001)
Enantioselective intermolecular [2+2]-photocycloaddition reactions of alkenes and a 2-quinolone in solution
T Bach et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
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