期刊
NEW JOURNAL OF CHEMISTRY
卷 45, 期 23, 页码 10150-10159出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj01227d
关键词
-
资金
- University of Ottawa
- NSERC-DG
The ever-growing demand for cleaner and higher-performing energetic materials has led to a quest to replace toxic metal-based traditional energetic compounds. This review examines strategies for the design and synthesis of next-generation nitrogen-rich, green primary explosives, focusing on potassium-based energetic salts, metal-free ionic energetic salts, and metal-free covalent energetic materials. Different combinations of nitrogen-rich frameworks and energetic substituents are highlighted for their explosive performance, initiability, safety, and environmental impact, along with key parameters associated with energetic materials.
The evergrowing demand for cleaner, high-performing energetic materials (EMs) has led to a quest for replacement of currently used toxic metal-based traditional energetic compounds such as lead azide and lead styphnate. As such, significant effort has been placed on the implementation of nitrogen-rich frameworks as cleaner and safer alternatives to the environmentally harmful EMs. This review examines strategies for the design and synthesis of next-generation nitrogen-rich, green primary explosives. Three categories of this class of materials are examined, namely potassium-based energetic salts, metal-free ionic energetic salts and metal-free covalent energetic materials. Within each subsection, different combinations of nitrogen-rich frameworks and energetic substituents are highlighted in terms of their explosive performance, initiability, safety and environmental impact. As well, a brief summary and description of key parameters associated with energetic materials is also provided.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据