期刊
NEW JOURNAL OF CHEMISTRY
卷 45, 期 23, 页码 10287-10295出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj01046h
关键词
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资金
- Russian Science Foundation [18-73-10065]
- Russian Science Foundation [18-73-10065] Funding Source: Russian Science Foundation
A directed synthesis of the first nitrile-rich dye showing visible-light-induced negative photochromism in aqueous medium was successfully achieved, demonstrating the color change of an aqueous solution from yellow to magenta by varying pH. The synthesized dye was found to be a thermally unstable photochrome that could be controlled by pH regulation, revealing a new direction in the investigation of nitrile-rich negative photochromes.
A directed synthesis of the first nitrile-rich dye showing visible-light-induced negative photochromism in aqueous medium was implemented. The possibility to change the color of an aqueous solution from yellow to magenta by varying the pH from 5 to 8 was shown. The synthesized dye was found to be a thermally unstable photochrome (T-type) whose photoinduced form returned to the initial state following the first order kinetic equation in the dark at room temperature. It was possible to change the dark reaction rate in a wide range and to block the photochromic process by pH regulation. The calculated pK(a)(1) of the initial form was more than 2.5 units higher than the pK(a)(1S) of the photoinduced form, which indicated the photoacidity of the dye in aqueous medium. This allowed the pH of the solution on 1.2 pH units to be reversibly changed under visible light irradiation, followed by dark relaxation. The obtained results revealed a new direction in the investigation of nitrile-rich negative photochromes, namely, the synthesis of water-soluble multicolor molecular switching systems sensitive to several factors.
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