期刊
GREEN CHEMISTRY
卷 23, 期 12, 页码 4421-4429出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc00515d
关键词
-
资金
- National Centre for Research and Development, Poland (Leader program) [LIDER/24/0100//L-9/17/NCBR/2018]
- National Agency for Academic Exchange of Poland (Academic International Partnerships program) [PPI/APM/2018/1/00004]
The dicationic and tricationic ionic liquids, synthesized by proton transfer from sulfuric acid and corresponding di- and triamines, show potential as Bronsted acidic catalysts in biodiesel production. These new ionic liquids are cost-effective and highly acidic, outperforming sulfuric acid and other catalysts in catalytic esterification reactions by absorbing water and phase-separating the ester. The interplay between acidity and physical properties, such as density and viscosity, enables easy phase separation of water from the ester, while substrate scope and recycling studies demonstrate their robustness and recyclability as catalysts.
Dicationic and tricationic ionic liquids, synthesised by proton transfer from sulfuric acid and corresponding di- and triamines, were characterised and used as Bronsted acidic catalysts in biodiesel production. It has been demonstrated that the new ionic liquids are less expensive than those based on monoamines (even on triethylamine) and are highly acidic. Their performance in a model catalytic esterification reaction surpassed that of sulfuric acid and other literature reports, due to the capability of the ionic liquids to absorb water while phase-separating the ester, thereby shifting the reaction equilibrium towards products. The overall catalytic performance was an interplay between acidity (quantified by Gutmann AN) and physical properties: density and viscosity, which enabled easy phase separation, thereby separating water from the ester. The substrate scope and recycling studies have demonstrated that the new ionic liquids are robust and recyclable catalysts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据