Metal Oxide/Nitrogen-Doped Carbon Catalysts Enables Highly Efficient CO2 Electroreduction

The metal oxide/nitrogen-doped carbon (NC) compounds zirconium oxide/NC (ZrO2/NC) and cerium oxide/NC (CeO2/NC) were synthesized via the pyrolysis of polyaniline on the metal oxide surface. The characterization of the ZrO2/NC and CeO2/NC catalysts showed more active CO2 reduction reaction activity than that of NC catalyst without metal oxide. Gas chromatography analysis revealed that CO and H-2 were the primary products, and no liquid-phase products were detected via proton nuclear magnetic resonance spectroscopy or high-performance liquid chromatography. The maximum Faraday efficiency of ZrO2/NC reached 90% at - 0.73 V (vs. RHE), with the current density of CO at 5.5 mA/cm(2); this Faraday efficiency value was higher than that of NC (41%), with the current density of CO at 3.1 mA/cm(2). The interaction between the metal oxide and carbon allowed the efficient formation of defect sites, especially imine-type nitrogen, strengthening the adsorption of the key reaction intermediate CO2 center dot- and thus promoting the CO2 reduction reaction.

Automated summary

The synthesis of metal oxide/nitrogen-doped carbon compounds enhances the activity of CO2 reduction reaction and promotes the generation of CO and H2 as primary products. The efficiency and current density of the metal oxide/nitrogen-doped carbon compounds are higher than those of nitrogen-doped carbon alone. The interaction between metal oxides and carbon facilitates the formation of defect sites, particularly imine-type nitrogen, enhancing the adsorption of key reaction intermediates and promoting the CO2 reduction reaction.