The preparation of three-dimensional flower-like TiO2/TiOF2 photocatalyst and its efficient degradation of tetracycline hydrochloride

A kind of high-efficiency photocatalyst of the three-dimensional flower-like TiO2/TiOF2 was synthesized by a one-step hydrothermal method. XRD, FE-SEM, EDS, HTEM, BET, XPS, PL, and UV-Vis-DRS were utilized to characterize the photocatalyst. The photocatalyst of TiO2/TiOF2 shows a narrow band gap of 2.8 eV. The generation of Ti3+ and an oxygen vacancy (O-v) in the photocatalyst are helpful to increase the absorption of visible light, and to inhibit faster charge recombination by capturing photogenerated carriers. Through the degradation of tetracycline hydrochloride (TCH) under simulated sunlight, the photocatalytic activity and stability of the synthesized samples were investigated. The results showed that the removal rate of tetracycline hydrochloride was 59% only in 0.5 h of dark reaction and 85% in 0.5 h of simulated sunlight. The removal efficiency of the photocatalyst for the adsorption and photocatalytic degradation of TCH is higher than that of the single TiO2, TiOF2, and Degussa P25. The synthesized three-dimensional flower-like TiO2/TiOF2 has great application potential in the treatment of antibiotic wastewater.

Automated summary

A high-efficiency three-dimensional flower-like TiO2/TiOF2 photocatalyst was synthesized by a one-step hydrothermal method, with a narrow band gap and the ability to inhibit charge recombination by capturing photogenerated carriers, showing high removal efficiency in simulated sunlight experiments.