Evaluation of BaCo0.4Fe0.4Zr0.2-xNixO3-δ perovskite cathode using nickel as a sintering aid for IT-SOFC

In this research work, BaCo0.Fe-4(0).4Zr0.2-xNixO3-delta (x = 0, 0.01, 0.02, 0.03, 0.04) perovskite cathode material for IT-SOFC is synthesized successfully using a combustion method and sintered at low temperature. The effects of nickel as a sintering aid on the properties of BaCo0.Fe-4(0).Zr-4(0).O-2(3-delta) are investigated through different characterization methods. The addition of nickel increased the densification and grain growth at a lower sintering temperature 1200 degrees C. XRD analysis confirms a single phase of BaCo0.Fe-4(0).Zr-4(0).O-2(3-delta), and an increase in crystalline size is observed. SEM micrographs show formation of dense microstructure with increased nickel concentration. TGA analysis revealed that BaCo0.Fe-4(0).4Zr0.2-xNix cathode materials are thermally stable within the SOFC temperature range, and negligible weight loss of 2.3% is observed. The bonds of hydroxyl groups and metal oxides are confirmed for all samples through FTIR analysis. The highest electrical properties are observed for BaCo0.Fe-4(0).4Zr0.2-xNix (x = 0.04) due to increased densification and electronic defects compared to other compositions. The maximum power density of 0.47 W cm(-2) is obtained for a cell having cathode material BaCo0.Fe-4(0).4Zr0.2-xNix (x = 0.02) owing to its permeable and well-connected structure compared to others.

Automated summary

The BaCo0.Fe-4(0).4Zr0.2-xNixO3-δ perovskite cathode material was successfully synthesized using a combustion method and sintered at low temperature, with the addition of nickel enhancing densification and grain growth at 1200 degrees C. XRD analysis showed a single phase and increased crystalline size, SEM micrographs displayed a dense microstructure with higher nickel concentration, and TGA analysis indicated thermal stability within the SOFC temperature range with minimal weight loss. The most promising electrical properties were observed for BaCo0.Fe-4(0).4Zr0.2-xNix (x = 0.04) due to increased densification and electronic defects, while a cell using BaCo0.Fe-4(0).4Zr0.2-xNix (x = 0.02) achieved the highest power density of 0.47 W cm(-2) attributed to its permeable and well-connected structure.