4.6 Article

Flexible temperature sensors made of aligned electrospun carbon nanofiber films with outstanding sensitivity and selectivity towards temperature

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MATERIALS HORIZONS
卷 8, 期 5, 页码 1488-1498

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d1mh00018g

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The use of ACNF films for flexible temperature sensor applications has shown outstanding performance with high sensitivity, accuracy, linearity, fast response time, and long-term durability when prepared at low carbonization temperatures. The ACNF sensor's lower electrical conductivity compared to conventional sensors enhances temperature sensing performance, making it suitable for human health monitoring.
Continuous real-time measurement of body temperature using a wearable sensor is an essential part of human health monitoring. Electrospun aligned carbon nanofiber (ACNF) films are employed to assemble flexible temperature sensors. The temperature sensor prepared at a low carbonization temperature of 650 degrees C yields an outstanding sensitivity of 1.52% degrees C-1, high accuracy, good linearity, fast response time and excellent long-term durability. Moreover, it exhibits high discriminability towards temperature amidst other unwanted stimuli and maintains its original performance even after repeated stretch/release cycles because of highly-aligned structures. The correlation between the atomic structure and the temperature sensing performance of ACNF sensors is established. Contrary to conventional highly conductive temperature sensors, the ACNF sensor with a low electrical conductivity prepared at a low carbonization temperature ameliorates the temperature sensing performance. This anomaly is explained by (i) the smaller and more disordered sp(2) carbon crystallites yielding a high negative temperature coefficient, (ii) a larger number of defects, and (iii) a higher pyridinic-N content generating abundant entrapped and localized electrons which are activated once sufficient thermal energy is available. Flexible ACNF sensor's overall performance is among the best-known carbon material-based flexible temperature sensors, demonstrating potential applications in emerging healthcare and flexible electronics technologies.

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