期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 50, 页码 6205-6208出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01420j
关键词
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资金
- Newcastle University Academic Track (NUAcT) Fellowship
- Royal Society of Chemistry Research Enablement Grants [E20-5153]
- EPSRC [EP/R021503/1]
The authors report the synthesis and structure of the first monomeric MeLi complex enabled by a new hexadentate neutral amine ligand.
Methyllithium (MeLi) is the parent archetypal organolithium complex. MeLi exists as aggregates in solutions and solid states. Monomeric MeLi is postulated as a highly reactive intermediate and plays a vital role in understanding MeLi-mediated reactions but has not been isolated. Herein, we report the synthesis and structure of the first monomeric MeLi complex enabled by a new hexadentate neutral amine ligand.
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