期刊
ORGANIC CHEMISTRY FRONTIERS
卷 8, 期 10, 页码 2174-2181出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00018g
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A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes exhibit high selectivity for Markovnikov hydrosilylations, while cobalt complexes provide excellent anti-Markovnikov selectivity. Both systems are highly efficient and tolerant to a wide range of functional groups.
A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes of amine-iminopyridine ligands are selective for Markovnikov hydrosilylations (branched/linear up to >99 : 1), while the cobalt complexes bearing the same type of ligands provide excellent levels of anti-Markovnikov selectivity (linear/branched up to >99 : 1). Both systems exhibit high efficiency and wide functional group tolerance.
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