期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 51, 页码 6316-6319出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc02040d
关键词
-
Two different multinuclear metal hydrides were isolated in this study, and it was found that there is hydride ligand exchange between calcium and strontium centers, with a higher affinity of the hydride ligand toward calcium.
A trinuclear strontium hydride [(Me(4)TACD)(3)Sr-3(mu(2)-H)(4)(thf)][B(C6H3-3,5-Me-2)(4)](2) (Me(4)TACD = 1,4,7,10-tetramethyltetraazacyclododecane) and a mixed calcium strontium hydride [(Me(4)TACD)(2)CaSr(mu-H)(2)(thf)][B(C6H3-3,5-Me-2)(4)](2) were isolated by hydrogenolysis of cationic benzyl precursors. A solution of [(Me(4)TACD)(2)CaSr(mu-H)(2)(thf)][B(C6H3-3,5-Me-2)(4)](2) shows hydride ligand exchange between calcium and strontium centers and higher affinity of the hydride ligand toward calcium.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据