期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 55, 页码 6756-6759出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc01756j
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资金
- Deutsche Forschungsgemeinschaft (DFG)
A visible light-mediated photocatalyzed C-C-bond forming method has been developed for the benzylic C-H functionalization of phenolether containing synthetic building blocks based on a radical-cation/deprotonation strategy. This method enables the mild, selective generation of benzyl radicals in phenolic complex molecules and drug-like compounds, offering new opportunities in synthetic and medicinal chemistry.
A visible light-mediated photocatalyzed C-C-bond forming method for the benzylic C-H functionalization of phenolether containing synthetic building blocks based on a radical-cation/deprotonation strategy is reported. This method allows the mild, selective generation of benzyl radicals in phenolic complex molecules and drug-like compounds, providing new entries in synthetic and medicinal chemistry.
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