期刊
NEW JOURNAL OF CHEMISTRY
卷 45, 期 26, 页码 11506-11511出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj01797g
关键词
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资金
- National Natural Science Foundation of China (NSFC) [51672158]
- Distinguished Youth Foundation of Hubei Province [2019C FA 084]
- Educational office of Hubei Province [Q20201201]
- 111 Project [D20015]
Sodium vanadate, used as a novel anode material for lithium-ion batteries, demonstrates satisfactory capacity, ultra-long cycle life, excellent rate capability, and great potential for practical applications due to its superior comprehensive electrochemical performance and low cost.
Sodium vanadate, Na3VO4, is prepared for the first time as a new anode material for lithium-ion batteries (LIBs), showing satisfactory capacity, an ultra-long cycle life and excellent rate capability. When cycling at a current of 0.1 A g(-1), the Na3VO4 electrode delivers a high reversible capacity of 535.2 mA h g(-1) after 610 cycles. Then cycling at a current of 1 A g(-1), the Na3VO4 electrode still retains a discharge capacity of 208 mA h g(-1) after 2000 cycles. After rate performance testing from 0.1 to 1.6 A g(-1) over 210 cycles, the Na3VO4 electrode retains a satisfactory capacity of 350 mA h g(-1), when the current returns to 0.1 A g(-1). The superior comprehensive electrochemical performance and low cost of Na3VO4 endow it with great potential for practical applications in LIBs.
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