A multifunctional colorimetric sensor originating from a cadmium naphthalene diimide-based metal-organic framework: photochromism, hydrochromism, and vapochromism

A new cadmium metal-organic framework [Cd(IsoNDI)(ClO4)center dot H2O](n) (ZH-102, IsoNDI = N,N '-di(4-pyridylacylamino)-1,4,5,8-naphthalene diimide) has been synthesized under solvothermal conditions and characterized systematically by elemental analyses, IR spectroscopy, powder X-ray diffraction, and thermogravimetric analyses. Single-crystal X-ray diffraction analysis reveals that ZH-102 exhibits a 2D structure similar to a 'safety fence' that further stacks into a 3D supramolecular network, which is constructed by bridging of Cd-IsoNDI with perchlorate (ClO4-) anions and intermolecular interaction. Owing to the presence of electron-deficient NDI moieties and the generation of IsoNDI radicals, ZH-102 displays reversible photochromic properties under irradiation and heating (120 degrees C) and photocontrolled luminescence properties. In particular, ZH-102 also exhibited vapochromic behavior for detecting amines. Moreover, the ZH-102 showed that excellent heat causes hydrochromism properties with a color change from deep yellow to coffee color when heated at 200 degrees C. Therefore, ZH-102 possesses multiple chromic properties and could be used as a colorimetric sensor, which provides a new route to design functional MOFs.

Automated summary

The newly synthesized cadmium metal-organic framework ZH-102 exhibits multiple color-changing properties and can be used as a colorimetric sensor, providing a new approach for designing functional MOFs.