期刊
ORGANIC CHEMISTRY FRONTIERS
卷 8, 期 16, 页码 4490-4495出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1qo00790d
关键词
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资金
- Natural Science Foundation of Zhejiang Province [LY19B020016]
A metal-free oxidative cyclization of trifluoroacetimidohydrazides with methylhetarenes has been developed for the efficient synthesis of 3-hetaryl-5-trifluoromethyl-1,2,4-triazoles. This protocol features readily accessible starting materials, a broad substrate scope, high efficiency, and scalability, providing a facile and straightforward route to valuable multi-functionalized 1,2,4-triazole derivatives.
A metal-free oxidative cyclization of trifluoroacetimidohydrazides with methylhetarenes for the efficient synthesis of 3-hetaryl-5-trifluoromethyl-1,2,4-triazoles has been developed. Notable features of this protocol include readily accessible starting materials, a broad substrate scope, high efficiency and scalability. The transformation provides a facile and straightforward route to valuable multi-functionalized 1,2,4-triazole derivatives.
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