期刊
NEW JOURNAL OF CHEMISTRY
卷 45, 期 27, 页码 11918-11926出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj02124a
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Canada Foundation for Innovation (CFI)
- Memorial University of Newfoundland
The effects of electron-donating and electron-withdrawing substituents on the electronic absorption, electrochemical redox, and solid-state supramolecular self-assembling properties of Ph-DTF and TTFV systems were investigated in this study.
Phenyl-dithiafulvene (Ph-DTF) and corresponding tetrathiafulvalene vinylogue (TTFV) systems functionalized with electron-donating methoxy and electron-withdrawing nitro groups, respectively, were synthesized and examined by UV-Vis absorption, cyclic voltammetric, and X-ray single-crystallographic analyses, in conjunction with density functional theory (DFT) calculations. Our studies unravel the donor/acceptor-substitution effects on the electronic absorption, electrochemical redox, and solid-state supramolecular self-assembling properties of these Ph-DTF and TTFV systems.
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