4.7 Article

Formation of silaimines from a sterically demanding iminophosphonamido chlorosilylene via intramolecular N-P bond cleavage

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CHEMICAL COMMUNICATIONS
卷 57, 期 55, 页码 6728-6731

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc02812j

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  1. Shorai Foundation for Science and Technology

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<P>The sterically demanding iminophosphonamido chlorosilylene [Ph2P(DipN)(2)]SiCl was synthesized and reacted with N- and Fe-nucleophiles, unexpectedly forming corresponding silaimine derivatives. This process involves the ring-opening rearrangement of three-coordinated silylene intermediates that proceeds via intramolecular N-P bond cleavage.</P>
The sterically demanding iminophosphonamido chlorosilylene [Ph2P(DipN)(2)]SiCl (Dip = 2,6-diisopropylphenyl) was synthesized and fully characterized using NMR spectroscopy and X-ray crystallography. Substitution reactions of [Ph2P(DipN)(2)]SiCl with N- and Fe-nucleophiles led to the unexpected formation of the corresponding silaimine derivatives. This process involves the ring-opening rearrangement of three-coordinated silylene intermediates that proceeds via intramolecular N-P bond cleavage.

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