4.6 Article

Control of the Cu ion species in Cu-SSZ-13 via the introduction of Co2+ co-cations to improve the NH3-SCR activity

期刊

CATALYSIS SCIENCE & TECHNOLOGY
卷 11, 期 14, 页码 4838-4848

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cy00623a

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资金

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning (MSIP) [NRF-2016R1A5A1009592]

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By introducing Co2+ co-cations onto Cu-SSZ-13 catalyst, the reactivity of CuCo-SSZ-13 catalyst can be enhanced, demonstrating higher SCR reactivity compared to conventional Cu-SSZ-13 catalyst under both low- and high-temperature conditions.
Cu-SSZ-13 has been successfully commercialized as a NOx removal catalyst for selective catalytic reduction with NH3 (NH3-SCR) in after-treatment systems. However, as global regulations on NOx emissions are becoming more stringent, the development of catalysts with higher NOx abatement ability is becoming more important. Herein, we propose a new strategy to enhance the reactivity of Cu-SSZ-13 by tuning the Cu ions in SSZ-13 zeolite. CuCo-SSZ-13 catalysts were synthesized by introducing Co2+ co-cations prior to loading Cu ions onto Cu-SSZ-13. The pre-loaded Co2+ co-cations induce the Cu ions to exist as more reactive species (Z-[Cu2+-OH-]) rather than less active species (2Z-Cu2+), which are classified by the number of adjacent framework Al atoms in SSZ-13. The designed CuCo-SSZ-13 catalysts demonstrate higher SCR reactivity than the conventional Cu-SSZ-13 catalyst under both low- and high-temperature conditions.

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