期刊
ECOMAT
卷 3, 期 3, 页码 -出版社
WILEY
DOI: 10.1002/eom2.12099
关键词
additive; carbon nanotube; multifunctional; perovskite solar cells; spiro-OMeTAD
类别
资金
- Sichuan Provincial Science and technology support project [2020YFG0102]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [19HASTIT049]
- National Natural Science Foundation of China [51771125]
- National Science Foundation for Young Scientists of China [61704048]
The hole transport layer (HTL) is crucial for the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs). By incorporating CNT:TiO2, the spiro-OMeTAD+CNT:TiO2 not only enhances conductivity significantly, but also effectively passivates the crystal defects of the perovskite layer. The optimized PSCs with spiro-OMeTAD+CNT:TiO2 HTL achieved a peak PCE of 21.53%, much higher than conventional spiro-OMeTAD based PSCs and showed improved stability.
Hole transport layer (HTL) is very important for the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs). As current state-of-the-art HTL, Li-TFSI doped spiro-OMeTAD often suffers low conductivity and the hydrolysis of the additive Li-TFSI, which significantly hinders the further improvement of PCE of PSCs. Besides, conventional spiro-OMeTAD has no functional of directly passivating the perovskite crystal defects. Herein, multifunctional TiO2 nanoparticles (NPs)-modified CNT (CNT:TiO2) doped spiro-OMeTAD (spiro-OMeTAD+CNT:TiO2) HTL is reported for the first time. The incorporated CNT:TiO2 not only significantly increases the conductivity of spiro-OMeTAD+CNT:TiO2, but also effectively passivates the crystal defects of perovskite layer. The optimized PSCs with spiro-OMeTAD+CNT:TiO2 HTL achieved a peak PCE of 21.53%, much higher than that (17.90%) of the conventional spiro-OMeTAD based PSCs and also show significantly improved stability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据