期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 59, 页码 7292-7295出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc02061g
关键词
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资金
- National Natural Science Foundation of China [21971091, 21901089]
- Natural Science Foundation of Jiangxi Province [20192ACB20013, jxsq2018106041, 20192BAB213003]
The study introduces a solid-solution strategy and demonstrates how related yet non-isostructural crystalline host-guest compounds can form molecular solid solutions. This strategy effectively modulates molecular motion and phase transition in them.
By utilizing a supramolecular complex rather than an individual molecule as a deformable and elastic substitutional component, we put forward a solid-solution strategy and demonstrate an example of how two related yet non-isostructural crystalline host-guest compounds can form molecular solid solutions. Interestingly, such a strategy can effectively and continuously modulate the molecular motion and phase transition in them, as revealed by the variable-temperature/frequency dielectric responses.
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