Single-crystal-to-single-crystal transformation of tetrathiafulvalene-based hydrogen-bonded organic frameworks

The design and synthesis of a hydrogen-bonded organic framework (HOF) based on tetrathiafulvalene tetracarboxylic acid is reported. The resultant HOF can undergo single-crystal-to-single-crystal transformation to form another two isomers. The structural characteristics and the redox properties of the HOFs were conveniently tailored utilizing the transformation of the phases.

Automated summary

The design and synthesis of a hydrogen-bonded organic framework based on tetrathiafulvalene tetracarboxylic acid is reported, which can undergo single-crystal-to-single-crystal transformation to form two isomers. The structural characteristics and redox properties of the HOFs were conveniently tailored using the transformation of phases.