期刊
GREEN CHEMISTRY
卷 23, 期 14, 页码 5031-5036出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc01658j
关键词
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资金
- Innovation and Talent Recruitment Base of New Energy Chemistry and Device [B21003]
- Hubei Technological Innovation Project [2019ACA125]
A novel family of electron donors benzofuro[2,3-b]indoles were successfully synthesized through a bimetallic catalysis strategy involving CoCl2/Cu(OTf)2, which showed superior efficiency and potential for further research. This method outperformed traditional multi-step synthesis approaches and demonstrated promising photophysical properties for potential applications in deep-blue organic light-emitting diodes.
Benzofuro[2,3-b]indoles, apart from their attractive biological features, constitute a novel family of electron donors for electroluminescent materials. Reported herein is the establishment of a strategy involving bimetallic catalysis to form such pi-conjugated extended frameworks, specifically via the CoCl2/Cu(OTf)(2)-catalyzed double aerobic oxidative cycloaddition of indoles with p-hydroquinone ester. The crucial and distinct roles of the two metals salts and the alcohol solvent were clarified. This oxidation system enabled the disruption of the well-established acid-catalyzed quinone-indole [3 + 2] cycloaddition reaction favoring benzofuro[2,3-b]indolines and is superior to previously known multi-step synthetic methods involving Pd-catalyzed cross-coupling with pre-functionalized (pseudo)halides. Moreover, the photophysical properties of the product were preliminarily investigated, the results of which suggested the potential of these polycyclic heteroaromatics to be used in efficient deep-blue organic light-emitting diodes.
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