期刊
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
卷 9, 期 4, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2021.105790
关键词
Noble metals; Deactivation; Titania; Heat treatment; Hydrocarbons
资金
- National Natural Science Foundation of China [21908236]
- China Ministry of Science and Technology [2016YFA0202802]
The study demonstrates that thermal oxidative aging and reduction strategy can reverse the sintering of Rh/TiO2 catalyst and significantly affect the catalytic performance towards methane dry reforming. The oxidative aging process impacts the mobilization of Rh species across TiO2, while reduction temperature influences oxymetal activation and electronic structure of Rh NPs, associated with carbon formation.
Noble metal nanoparticles (NPs) exhibit high reactivity towards hydrocarbon reforming, however, suffer from agglomeration and poisoning issues (e.g., carbon deposition). A facile and environmental approach to rejuvenate noble metal catalysts is techniques using thermal redox cycles. Here we demonstrate that in situ thermal oxidative aging and reduction strategy can reverse the sintering of Rh/TiO2 catalyst and meanwhile this redox process significantly affects the catalytic performance towards methane dry reforming (DRM). The oxidative aging process has substantial impact on the mobilization of Rh species across TiO2, and thus the degree of oxymetal activation and the Rh NPs size. In the subsequent reductive process, reduction temperature not only influences oxymetal activation but also the electronic structure of Rh NPs, which directly relates to the carbon formation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据