期刊
RSC ADVANCES
卷 11, 期 35, 页码 21235-21247出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ra03064g
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资金
- Dalian Research Institute of Petroleum and Petrochemicals (SINOPEC) [119010-1]
Innovative hydrothermal method was successfully applied for synthesizing hierarchical ZSM-5/beta composite zeolites, which exhibited superior characteristics and catalytic performance. The pore structure and acid sites of the composite can be adjusted by changing the mass ratio, providing new possibilities for the cracking reaction.
An innovative hydrothermal method has been successfully applied to the synthesis of hierarchical ZSM-5/beta composite zeolites with different mass ratios. Firstly, the ZSM-5 zeolites were coated with amorphous silica and aluminum species by a spray drying process. Then, the precursor powder was hydrothermally crystallized for only 1-2 days with the addition of tetraethyl ammonium hydroxide (TEAOH). The obtained products were characterized by XRD, SEM, TEM, N-2 physical adsorption-desorption, Al-27 MAS NMR, ICP, pyridine-IR and NH3-TPD techniques. The characterization results imply that the ZSM-5/beta composite zeolites exhibit hierarchical-pores, higher external surface areas and larger mesopore volumes as compared to those of the pure ZSM-5 and beta zeolite. Moreover, the pore structure and acid sites of the ZSM-5/beta composite can be adjusted by changing the mass ratio of ZSM-5/beta. Finally, the ZSM-5/beta composite catalysts exhibit good catalytic performances in the cracking of 1,3,5-triisopropylbenzene (1,3,5-TIPB).
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