期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 9, 期 28, 页码 15724-15733出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ta03177e
关键词
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资金
- DOE-BES grant [DE-SC0020125]
- U.S. Department of Energy Office of Science User Facility [DE-AC02-05CH11231]
- U.S. Department of Energy (DOE) [DE-SC0020125] Funding Source: U.S. Department of Energy (DOE)
Supported single-atom and small cluster catalysts are popular in heterogeneous catalysis due to their high metal atom utilization and superior performance. Research shows that platinum single atoms are stabilized in the presence of tin, especially on the hydroxylated indium tin oxide support, reducing sintering and increasing stability. This finding offers a promising approach for designing single-atom catalysts on electrically conducting supports and understanding the impact of functional groups on cluster catalyst adhesion.
Supported single-atom and small cluster catalysts have become highly popular in heterogeneous catalysis. These catalysts can maximize the metal atom utilization while still showing superior catalytic performance. One of the main challenges in producing these small cluster catalysts is their low binding strength with the support, which causes these small clusters to sinter into larger nanoparticles. We have used first-principles simulations to study small Pt-n (n: 1,2,3) clusters on indium oxide, tin doped indium oxide, and hydroxylated tin doped indium oxide. We report that the Pt-n cluster is stabilized in the presence of tin and that this is especially the case for Pt single atoms on the hydroxylated indium tin oxide support, which are anchored to the support via the hydroxyl group. On this support, the Pt single atoms become more stable than Pt-2 and Pt-3 clusters, hence decreasing sintering. These findings provide a promising way to design single-atom catalysts on electrically conducting supports for electrocatalytic applications and to better understand how functional groups on supports can increase the adhesion of cluster catalysts.
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