期刊
CRYSTENGCOMM
卷 23, 期 30, 页码 5208-5213出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1ce00679g
关键词
-
资金
- National Natural Science Foundation of China [12004289]
- Hubei Provincial Department of Education [Q20201512]
This study presents a novel class of hybrid organic-inorganic magnetic perovskites composed of metal ions and organic ligands, exhibiting magnetic properties.
For the hybrid organic-inorganic perovskites with the general formula of A(2)M(II)X(4) (A = methylammonium; M-II = Mn, Cu and Co; X = Cl), the arrangement of metal ions and organic ligands leads to a delicate balance of space, spin and charge, which results in diverse properties. In this paper, we reported a group of hybrid organic-inorganic perovskite single crystals of (CH3NH3)(2)MnCl4, (CH3NH3)(2)CuCl4 and (CH3NH3)(2)CoCl4 grown by a simple solution evaporation method. Magnetic measurements show that all the single crystals display magnetic ordering at low temperature. Our results reveal a novel group of hybrid organic-inorganic magnetic perovskites.
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