4.6 Review

Research progress on methane conversion coupling photocatalysis and thermocatalysis

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Direct experimental detection of hydrogen radicals in non-oxidative methane catalytic reaction

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Direct oxidation of methane to oxygenates on supported single Cu atom catalyst

Xuan Tang et al.

Summary: Cu-1/ZSM-5 single atom catalyst shows high activity and selectivity in direct CH4 oxidation, with each isolated Cu atom stabilized by four O moieties on the ZSM-5 support forming a uniform Cu-1-O-4 entity as the active site.

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Xin Li et al.

Summary: The Z-scheme ZnO/Au/g-C3N4 micro-needle film enhanced by the Local Surface Plasma Resonance (LSPR) effect demonstrated excellent photocatalytic performance and reusability in the photoreduction of CO2 into CO under UV-vis light irradiation. The material achieved a high CO production rate after 8 hours of reaction time, which was significantly higher than that of the pure ZnO film. The combination of factors such as the electric field at the g-C3N4/ZnO interface, the role of Au NPs as electron-transfer bridges and LSPR excited sources, and in-situ FTIR technique investigation contribute to the enhanced electron transfer efficiency and overall photocatalytic performance.

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Visible-light driven room-temperature coupling of methane to ethane by atomically dispersed Au on WO3

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Summary: The combination of gold as co-catalyst and singlet oxygen as oxidant is an effective strategy for selectively converting methane. Atomically dispersed Au on WO3 showed enhanced visible light photocatalytic conversion of CH4, with a high selectivity. Investigation of the radicals-pathway mechanism of methane coupling and theoretical calculations on the electronic structure of Au/WO3 were conducted for a better understanding of the process.

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An Li et al.

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Pt1-O4 as active sites boosting CO oxidation via a non-classical Mars-van Krevelen mechanism

Yang Lou et al.

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Catalytic cycle of the partial oxidation of methane to methanol over Cu-ZSM-5 revealed using DFT calculations

Xi Yu et al.

Summary: Density functional theory calculations were used to investigate the catalytic cycle of methane conversion to methanol over [Cu-2(O-2)](2+) and [Cu-2(mu-O)](2+) active sites in the Cu-ZSM-5 catalyst. The [Cu-2(O-2)](2+) site was found to be active for the partial oxidation of methane to methanol with low energy barriers. The reactivity towards methane oxidation was influenced by the electronic properties of the reactive O atoms in the active site.

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Zhongshan Yang et al.

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