期刊
POLYMER CHEMISTRY
卷 12, 期 32, 页码 4593-4612出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1py00596k
关键词
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资金
- National Centre for Research and Development (Warsaw, Poland) - INNOCHEM project [POIR.01.02.00-00-0038/16-00]
Frontal polymerisation has gained increasing interest in various applications in recent years, with its ability to cure thick samples with different fillers using a reasonable portion of energy. It offers promising applications in materials science, industry, and 3D structure preparation. Additionally, the combination of frontal polymerisation and light curing provides a convenient and versatile method, especially for heat sensitive materials or dentistry applications.
In recent years, frontal polymerisation has found a growing interest in many applications. Thus, its ability to cure thick samples with different fillers up to 50% by local application of a reasonable portion of energy makes this polymerisation approach very promising. It can find many applications in materials science and industry as well as in the preparation of 3D structures. Herein, we present recent achievements in the field of frontal photopolymerisation and phototriggered frontal thermal polymerisation. A light application allows full control of the curing process. The combination of frontal polymerisation and light curing provides a convenient and versatile method to trigger frontal polymerisation, especially in heat sensitive materials or dentistry applications. Moreover, in this review, we focused on the photoinitiating systems in frontal polymerisation, their mechanism of action, components, and applications, dividing them according to the type of polymerisation: free-radical polymerisation, ring-opening cationic polymerisation and other minor types.
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