4.5 Article

Ce:YAG Transparent Ceramics Enabling High Luminous Efficacy for High-power LEDs/LDs

期刊

JOURNAL OF INORGANIC MATERIALS
卷 36, 期 8, 页码 883-892

出版社

SCIENCE PRESS
DOI: 10.15541/jim20200727

关键词

LEDs/LDs illumination; photoluminescence; Ce: YAG; ceramic phosphor

资金

  1. National Key R&D Program of China [2017YFB0310500]
  2. Key Research Project of the Frontier Science of the Chinese Academy of Sciences [QYZDB-SSW-JSC022]

向作者/读者索取更多资源

Ce:YAG transparent ceramics combined with blue LEDs/LDs allow for adjustment of emission spectra and color coordinates of assembled devices, providing flexibility to transition from cool to warm white light for high power applications. The materials used, fabrication methods, and thermal properties of the ceramics were studied in depth, demonstrating the promising potential of Ce:YAG transparent ceramics as a color conversion material for future high power lighting and display applications.
Ce:YAG transparent ceramics could be combined with blue LEDs/LDs, for applications of high power white LEDs/LDs. In this study, it is found that by adjusting the thickness of Ce:YAG transparent ceramics and the doping concentration of Ce3+, the emission spectra and color coordinates of the assembled devices can be adjusted from the cold white region to the warm white region. (CexY1-x)(3)Al5O12 ( x=0.0005, 0.0010, 0.0030, 0.0050, 0.0070 and 0.0100) transparent ceramics was fabricated by a solid state reaction method, with the high pure (=99.99%) commercial powders alpha-Al2O3, Y2O3 and CeO2 using as raw materials. The ceramic green bodies were sintered in 1750. for 20 h under vacuum of 5.0x10(-5) Pa, and the ceramics were annealed at 1450 degrees C for 10 h in the muffle furnace. The in-line transmittance of double polished Ce:YAG ceramics is higher than 79% at 800 nm (0.2, 0.4, 1.0 mm in thickness, respectively). The thermal conductivity of Ce:YAG transparent ceramics decreases with the increase of measuring temperature and doping concentration. Thermal distribution of ceramics and LEDs with different thicknesses was simulated by the finite element method, and the thermal distributions of three packaging modes were compared. White light with chromaticity coordinates of (0.3319, 0.3827) and (0.3298, 0.3272) and luminous efficiency of 122.4 and 201.5 lm/W were prepared by combining transparent ceramics with LEDs/LDs. We combined Ce:YAG transparent ceramics and blue LEDs chips to produce 10 and 50 W mature lamps, which can be used for commercial purposes. Therefore, the Ce:YAG transparent ceramics is a highly promising color conversion material for high power lighting and displaying applications in the future.

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