期刊
GREEN CHEMISTRY
卷 23, 期 16, 页码 5797-5805出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1gc01902c
关键词
-
资金
- National Natural Science Foundation of China [21975090, 51802107, 52073110, 51872107]
The newly designed dual nickel/photocatalysis 2D covalent organic framework (COF) has successfully overcome the difficulties of recycling photosensitizers or nickel complexes, efficiently converting aryl bromides to aryl alkyl ethers with good substrate compatibility and functional group tolerance.
The efficient conversion of aryl bromides to the corresponding aryl alkyl ethers by dual nickel/photocatalysis has seen great progress, but difficulties of recycling the photosensitizer or nickel complexes cause problems of sustainability. Here, we report the design of a novel, highly stable vinyl bridge 2D covalent organic framework (COF) containing Ni, which combines the role of photosensitizer and reactive site. The as-prepared sp(2)c-COFdpy-Ni acts as an efficient heterogeneous photocatalyst for C-O cross coupling. The sp(2)c-COFdpy-Ni can be completely recovered and used repeatedly without loss of activity, overcoming the limitations of the prior methods. Preliminary studies reveal that strong interlayer electron transfer may facilitate the generation of the proposed intermediate sp(2)c-COFdpy-Ni-I in a bimolecular and self-sustained manner. This all-in-one heterogeneous photocatalyst exhibits good compatibility of substrates and tolerance of functional groups. The successful attempt to expand the 2D COFs with this new catalyst into photocatalytic organic transformation opens an avenue for photoredox/transition metal mediated coupling reactions.
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