期刊
EUROPEAN POLYMER JOURNAL
卷 93, 期 -, 页码 390-402出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2017.06.013
关键词
PEEK-PES copolymers; Chlorosulfonic acid; Copolymer electrolyte membranes; Impedance spectroscopy; PEMFC
资金
- Spanish Ministry of Economy and Competitiveness MINECO [MAT2016-78362-C4-3-R, MAT2013-46452-C4-3R]
- Community of Madrid [MATERYENER3CM S2013/MIT-2753, PILCONAER S2013/MAE-2975]
- Universidad Carlos III de Madrid, Spain
In this work we have developed new sulfonated cardo (lactonic group) PEEK-WC-PES random copolymers with different molar ratio. The degree of sulfonation was determined from elemental analysis and ion-exchange capacity (IEC). Sulfonation levels from 0.64 to 1 were easily achieved by varying and controlling the reaction conditions. Proton conductivity was evaluated by impedance spectroscopy (EIS). Activation energy for proton transport, determined by conductivity measurements ranged between 11 and 15 kJ mol(-1), suggesting a vehicular proton transport mechanism. The membrane with better performance in single fuel cell was PEEK-SWC-PES 70:30 with maximum power and current densities of 93.6 mW cm(-2) and 340 mA cm(-2), respectively.
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