期刊
EUROPEAN POLYMER JOURNAL
卷 94, 期 -, 页码 376-383出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2017.07.026
关键词
Shape memory polymers; Solution electrospinning; Cationic photopolymerization; Smart materials; UV curing reactions
资金
- University of the Basque Country UPV/EHU [UFI 11/56]
- Basque Government
A mat of fibers with shape memory effect is obtained using commercially available components and a simple electrospinning process. For obtaining this goal, a blend of diglycidyl ether of bisphenol A (DGEBA) and Polycaprolactone (PCL) is electrospun and the obtained mats are cured by UV radiation, avoiding the melting of the PCL component. The cationic photoinitiator based on iodonium salts, used for the first time in the electrospinning process, increases the solution conductivity and consequently the spinnability of the blend. The obtained mats show shape memory properties through several cycles, with shape fixity ratios that range from 95 to 99% and shape recovery ratios of between 88 and 100% respectively.
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