期刊
EUROPEAN POLYMER JOURNAL
卷 94, 期 -, 页码 136-142出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2017.06.043
关键词
Polyurethane; Carbon dioxide fixation; Sorbitol; Cyclic carbonate; Coatings
资金
- JONAS Joint Research Network on Advanced Materials and Systems, BASF SE, Ludwigshafen, Germany
- Ministerium fur Wissenschaft, Forschung and Kunst Baden-Wurttemberg, Stuttgart, Germany
The facile chemical fixation of 18 wt.% carbon dioxide by catalytic carbonation of sorbitol glycidyl ether, monitored by means of NMR and FTIR spectroscopy, affords sorbitol-based cyclic ether carbonate (SEC) as versatile intermediate for producing renewable non-isocyanate poly-hydroxydroxyurethane (NIPU) materials. In sharp contrast to the solid, crystalline and highly insoluble pure sorbitol tricarbonate (STC), melting above 200 degrees C close to its decomposition temperature, SEC is liquid at room temperature and fully miscible with a wide variety of poly-functional amine curing agents. Despite high SEC carbonate functionality (4.2 mol/kg), both gel time and pot-life time measurements confirm easy processing by curing SEC with polyfunctional aliphatic amines to produce new families of sorbitol-based NIPU materials. Particularly, blends combining flexible long-chain diamines such as dimer fatty acid based diamine (Priaminen (TM) 1074) or polyether triamine (Jeffamine (TM) T403), respectively, with rigid short-chain diamines such as 1,6-hexamethylene diamine (HMDA), 1,12-dodecyl diamine (DDA), 2,2,4-trimethylhex-amethylene diamine (TMHMDA) and isophorone diamine (IPDA), enable the simultaneous incorporation of soft and hard segments into NIPU networks. Moreover, miscible blends of SEC with STC remain liquid up to high STC content. Unparalleled by conventional bio-based NIPU chemistry, the curing of SEC or miscible SEC/STC blends, respectively, with IPDA yields sorbitol-based NIPU thermosets exhibiting significantly improved thermal and mechanical properties, as reflected by high glass transition temperatures surpassing 180 degrees C and Young moduli exceeding 4000 MPa.
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