期刊
INORGANICS
卷 9, 期 7, 页码 -出版社
MDPI
DOI: 10.3390/inorganics9070055
关键词
arene; osmium; half-sandwich complexes; homogeneous catalysis
资金
- Spanish Ministry of Economy, Industry and Competitiveness (MINECO) [CTQ2016-75986-P]
This review article focuses on the catalytic applications of arene-osmium(II) complexes, discussing transfer hydrogenation, hydrogenation, oxidation, and nitrile hydration reactions, as well as different C-C bond forming processes comprehensively, showing that they can achieve comparable or superior effectiveness in some instances compared to their ruthenium analogues.
Although the application of arene-osmium(II) complexes in homogeneous catalysis has been much less studied than that of their ruthenium analogues, different works have shown that, in some instances, a comparable or even superior effectiveness can be achieved with this particular class of compounds. This review article focuses on the catalytic applications of arene-osmium(II) complexes. Among others, transfer hydrogenation, hydrogenation, oxidation, and nitrile hydration reactions, as well as different C-C bond forming processes, are comprehensively discussed.
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