期刊
CHEMICAL COMMUNICATIONS
卷 57, 期 71, 页码 8945-8948出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc03589d
关键词
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A novel and cost-effective nickel-catalyzed ortho-C-Ar-H glycosylation reaction with high regioselectivity and excellent alpha-selectivity is described in this study. The method shows great functional group compatibility with various glycosides, demonstrating its synthetic potential. Mechanistic studies suggest that C-H activation could be the rate-determining step.
C-Aryl glycosides are of high value as drug candidates. Here a novel and cost-effective nickel catalyzed ortho-C-Ar-H glycosylation reaction with high regioselectivity and excellent alpha-selectivity is described. This method shows great functional group compatibility with various glycosides, showing its synthetic potential. Mechanistic studies indicate that C-H activation could be the rate-determining step.
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