期刊
CHEMICAL REVIEWS
卷 121, 期 14, 页码 8613-8684出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.0c00697
关键词
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资金
- Agencia Estatal de Investigacion (AEI)/FEDER, UE [CTQ2016-75960-P]
- Severo Ochoa Excellence Accreditation [SEV-2013-0319]
- FPI predoctoral fellowship
- European Research Council [835080]
- European Union [754510]
- AGAUR [2017 SGR 1257]
- CERCA Program/Generalitat de Catalunya
This review provides a comprehensive summary of major advances and discoveries in gold-catalyzed synthesis of highly strained carbocycles, including cyclopropanes, cyclopropenes, cyclobutanes, cyclobutenes, and their heterocyclic or heterosubstituted analogs, demonstrating the powerful application of homogeneous gold catalysis in constructing small ring compounds.
Three- and four-membered rings, widespread motifs in nature and medicinal chemistry, have fascinated chemists ever since their discovery. However, due to energetic considerations, small rings are often difficult to assemble. In this regard, homogeneous gold catalysis has emerged as a powerful tool to construct these highly strained carbocycles. This review aims to provide a comprehensive summary of all the major advances and discoveries made in the gold-catalyzed synthesis of cyclopropanes, cyclopropenes, cyclobutanes, cyclobutenes, and their corresponding heterocyclic or heterosubstituted analogs.
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