3d-4f Heterometallic cluster incorporated polyoxoniobates with magnetic properties

A series of 3d-4f heterometallic cluster incorporated polyoxoniobates (PONbs) with different magnetic properties were first made and characterized. This work not only provides a promising strategy to make new heterometallic cluster incorporated PONbs but also demonstrates an ideal model to probe how transition-metal ions influence the magnetic property of PONbs.

Automated summary

A series of 3d-4f heterometallic cluster incorporated polyoxoniobates with different magnetic properties were successfully synthesized and characterized in this study, providing a promising strategy for making new heterometallic cluster incorporated PONbs, and demonstrating an ideal model for investigating how transition-metal ions influence the magnetic properties of PONbs.